Conclusions
-
1.
Dipole moments have been determined for certain vinylalkyl(aryl)dimethoxysilanes.
-
2.
The measured values of the dipole moment could be correlated either with the sum of the substituentσ * values for either the alkyl or aryl group at the silicon atom.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
K. A. Adrianov, N. V. Delazari, N. A. Emel'kina, and T. P. Kramarenko, Vysokomol. Soedin.,A17, 2325 (1975).
L. Matasumura, Bull. Chem. Soc. Jpn.,35, 801 (1962).
C. W. N. Cumper, A. Melnikoff, and A. I. Vogel, J. Chem. Soc. A, 1966, 323.
C. W. N. Cumper and R. F. Rossiter, J. Phys. Chem.,76, 525 (1972).
L. A. Mai, G. Yu. Zueva, and I. Ya. Shtraus, Izv. Akad. Nauk LatvSSR, Ser. Khim.,1973, 302.
G. A. Gornowez, J. W. Ryan, and J. L. Speier, J. Org. Chem.,33, 2918 (1968).
R. Nagel, Diss. Abstrs.,12, 451 (1952); Chem. Abstrs.,47, 8635 (1953).
R. Corrini, B. Henner, and J. Massé, Bull. Soc. Chim. France,1968, 3013.
R. Nagle, Ch. Tamborski, and H. W. Post, J. Org. Chem.,16, 1768 (1951).
J. W. Smitt, Trans. Faraday Soc.,46, 394 (1950).
J. Timmermans, Physicochemical Constants of Pure Liquids, National Bureau of Standards (1951), Circular 514.
R. J. W. Le Fevre and P. Russel, Trans. Faraday Soc.,43, 374 (1947).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 91–94, January, 1978.
Rights and permissions
About this article
Cite this article
Andrianov, K.A., Papoushkova, Z., Khvalovskii, V. et al. Dipole moments of vinylalkyl(aryl)dimethoxysilanes. Russ Chem Bull 27, 79–81 (1978). https://doi.org/10.1007/BF01153213
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01153213