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Geometrical structures of certain ω-substituted acetophenones

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The bromoalkyl groups of the phenacyl bromides and theirω-methyl-substituted derivatives distribute themselves in equilibrium proportions between cis and gauche positions.

  2. 2.

    The aryl group rotates out of the carbonyl plane by as much as 70° under the action of two gaucheω substituents; a single substituent sterically suppresses one direction of rotation.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, I. I. Lapkin, I. M. Khamatullina, A. M. Kamalyutdinova, F. G. Saitkulova, S. G. Vul'fson & A. N. Vereshchagin

  2. Perm State University, USSR

    B. A. Arbuzov, I. I. Lapkin, I. M. Khamatullina, A. M. Kamalyutdinova, F. G. Saitkulova, S. G. Vul'fson & A. N. Vereshchagin

Authors
  1. B. A. Arbuzov
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  2. I. I. Lapkin
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  3. I. M. Khamatullina
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  4. A. M. Kamalyutdinova
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  5. F. G. Saitkulova
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  6. S. G. Vul'fson
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  7. A. N. Vereshchagin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 80–84, January, 1978.

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Arbuzov, B.A., Lapkin, I.I., Khamatullina, I.M. et al. Geometrical structures of certain ω-substituted acetophenones. Russ Chem Bull 27, 69–72 (1978). https://doi.org/10.1007/BF01153211

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  • DOI: https://doi.org/10.1007/BF01153211

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