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Heat of adsorption of ammonia by type E zeolites

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Measurement has been made of the heat evolved in the adsorption of ammonia on calcium, calcium-sodium, and sodium forms of type E zeolites.

  2. 2.

    The Ca2+ cations of type E zeolites are more active which respect to adsorbing ammonia molecules than are the Ca2+ ions of synthetic faujasites and type A zeolites.

  3. 3.

    The results obtained are analyzed in terms of lattice position differences in the calcium cations, of the type E zeolites and of zeolites of other types.

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Literature cited

  1. R. M. Barrer and R. M. Gibbons, Trans. Faraday Soc.,59, 491, 2569 (1963).

    Google Scholar 

  2. N. N. Avgul' and G. G. Muttik, Zeolites, Synthesis, Properties, and Applications [in Russian], Nauka, Moscow-Leningrad (1965), p. 75.

    Google Scholar 

  3. F. S. Stone and L. Whalley, J. Catal.,8, 173 (1967).

    Google Scholar 

  4. B. V. Romanovskii, K. V. Topchieva, L. V. Stolyarova, and A. M. Alekseev, Kinet. Katal.,12, 1003 (1971).

    Google Scholar 

  5. T. R. Brueva and A. L. Klyachko-Gurvich, in: Proceedings of the Sixth All-Union Conference on Calorimetry, Tbilisi, Metsniereba (1973), p. 186.

    Google Scholar 

  6. W. Schirmer, A. Grossmann, K. Fiedler, K.-H. Sichart, and M. Bülow, Chem. Techn.,22, No. 7, 405 (1970).

    Google Scholar 

  7. H. Stach, K. Fiedler, T. Peinze, and W. Schirmer, Z. Chem.,10, 473 (1970).

    Google Scholar 

  8. A. Cointot, P. Cartraud, and M.-C. Veyssiere, Bull. Soc. Chim. France,1973, 21.

  9. T. R. Brueva, Dissertation, Moscow, 1976.

  10. S. S. Khvoshchev and S. P. Zhdanov, Dokl. Akad. Nauk SSSR,196, 1391 (1971).

    Google Scholar 

  11. S. P. Zhdanov, N. N. Buntar'-Samulevich, and M. E. Ovsepyan, Dokl. Akad. Nauk SSSR,161, 384 (1965).

    Google Scholar 

  12. V. E. Skazyvaev, S. S. Khvoshchev, and S. P. Zhdanov, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 19.

  13. J. V. Smith, J. Chem. Soc.,1964, 3759.

  14. S. P. Zhdanov, V. E. Skazyvaev, S. S. Khvoshchev, and N. N. Samulevich, Zh. Prikl. Khim.,48, 39 (1975).

    Google Scholar 

  15. M. M. Dubinin, A. A. Isirikyan, G. U. Rakhmatkariev,and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1972, 1269.

  16. R. M. Barrer, Proc. Roy. Soc.,A167, 392 (1938).

    Google Scholar 

  17. J. W. Ward, J. Phys. Chem.,72, 4211 (1968).

    Google Scholar 

  18. U. Lohse, K.-H. Sichart, A. Grossmann, H. Stach, and W. Schirmer, Monatsber. Deutsch. Akad. Wiss. Berlin,13, 122 (1971).

    Google Scholar 

  19. J. V. Smith, Acta Crystallogr.,15, 835 (1962).

    Google Scholar 

  20. J. M. Bennet and J. V. Smith, Mater. Res. Bull.,3, No. 8, 633 (1968).

    Google Scholar 

  21. J. J. Pluth and J. V. Smith, Mater. Res. Bull.,7, No. 11, 1311 (1972).

    Google Scholar 

  22. K. Seff and D. P. Shoemaker, Acta Crystallogr.,22, 162 (1967).

    Google Scholar 

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Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, Academy of Sciences of the USSR, Leningrad

    S. S. Khvoshchev, V. E. Skazyvaev, S. P. Zhdanov & I. V. Karetina

Authors
  1. S. S. Khvoshchev
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  2. V. E. Skazyvaev
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  3. S. P. Zhdanov
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  4. I. V. Karetina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 23–28, January, 1978.

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Khvoshchev, S.S., Skazyvaev, V.E., Zhdanov, S.P. et al. Heat of adsorption of ammonia by type E zeolites. Russ Chem Bull 27, 16–20 (1978). https://doi.org/10.1007/BF01153199

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  • DOI: https://doi.org/10.1007/BF01153199

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