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ESR investigation of the hydrolysis of titanium(III) in aqueous hydrochloric acid solutions

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The ESR signal, with a g-factor of 1.938 and a line width of about 100 Oe, which arises in aqueous chloride solutions of titanium(III) at room temperature belongs to a monohydroxo complex of trivalent titanium in equilibrium with the hexaaquo complex.

  2. 2.

    The authors have used ESR to determine the equilibrium constant of the hydrolysis of titanium(III).

  3. 3.

    They have also determined the kinetic characteristics of the hydrolysis of titanium(III).

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Authors and Affiliations

  1. Department of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    V. F. Shuvalov, S. L. Solov'ev & Ya. S. Lebedev

  2. Ivanovo Chemico-technological Institute, USSR

    V. F. Shuvalov, S. L. Solov'ev & Ya. S. Lebedev

Authors
  1. V. F. Shuvalov
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  2. S. L. Solov'ev
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  3. Ya. S. Lebedev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 11–16, January, 1978.

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Shuvalov, V.F., Solov'ev, S.L. & Lebedev, Y.S. ESR investigation of the hydrolysis of titanium(III) in aqueous hydrochloric acid solutions. Russ Chem Bull 27, 5–9 (1978). https://doi.org/10.1007/BF01153196

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  • DOI: https://doi.org/10.1007/BF01153196

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