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Preparation and mass spectrometry of derivatives of 1-germa-3,5-cycloheptadiene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Derivatives of 1-germa-3,5-cyclopentadiene have been synthesized, and their properties studied.

  2. 2.

    Under electron impact, the 1-germa-3,5-cyclopentadiene compounds undergo carbenoid decomposition with the formation of GeRR' and C6H8 fragments, the charge distribution between these fragments being such as to indicate that the ionization potentials of the germylenes fall off in the order GeCl2 > Ge(Cl)C6H4CH3-4 > Ge(CH3)2 and Ge(C6H5)2.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. P. Kolesnikov, A. I. Ioffe, K. Uisassi, I. Tamash & O. M. Nefedov

  2. Central Chemical Scientific-Research Institute, Academy of Sciences of the Hungarian People's Republic, Budapest

    S. P. Kolesnikov, A. I. Ioffe, K. Uisassi, I. Tamash & O. M. Nefedov

Authors
  1. S. P. Kolesnikov
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  2. A. I. Ioffe
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  3. K. Uisassi
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  4. I. Tamash
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  5. O. M. Nefedov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1048–1051, May, 1977.

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Kolesnikov, S.P., Ioffe, A.I., Uisassi, K. et al. Preparation and mass spectrometry of derivatives of 1-germa-3,5-cycloheptadiene. Russ Chem Bull 26, 960–963 (1977). https://doi.org/10.1007/BF01152693

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  • DOI: https://doi.org/10.1007/BF01152693

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