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Reaction of sodium acetylide with trialkylstannols and hexaalkyldistannoxanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of sodium acetylide with trialkylstannanol and hexaalkyldistannoxanes has been investigated and it has been shown that reaction takes place through the intermediate stage of the formation of stannanolates.

  2. 2.

    Unlike the stannanols, the trialkystannanolates readily react with trialkylethynylstannanes to form hexaalkyldistannylacetylenes.

  3. 3.

    In the reaction of sodium acetylide with trialkylstannanols, trialkylalkoxystannanes, and hexaalkyl-distannoxanes, the sodium atom at the acetylene bond is more active than the hydrogen atom.

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Literature cited

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Author information

Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    N. V. Komarov, I. S. Guseva & F. P. L'vova

Authors
  1. N. V. Komarov
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  2. I. S. Guseva
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  3. F. P. L'vova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1479–1481, August, 1966.

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Komarov, N.V., Guseva, I.S. & L'vova, F.P. Reaction of sodium acetylide with trialkylstannols and hexaalkyldistannoxanes. Russ Chem Bull 15, 1424–1426 (1966). https://doi.org/10.1007/BF01151393

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  • DOI: https://doi.org/10.1007/BF01151393

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