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Synthesis of some (trimethylsiloxy) titanium compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By reaction between TiCl4 and sodium trimethylsiloxide tetrakistrimethylsiloxytitanium, chlorotristrimethylsiloxytitanium, and trichloro (trimethylsiloxy) titanium were prepared.

  2. 2.

    Dichlorobistrimethylsiloxytitanium was synthesized by the action of TiCl4 on tetrakistrimethylsiloxytitanium.

  3. 3.

    The mixed ester, butoxytristrimethylsiloxytitanium, was prepared by the reaction of chlorotristrimethylsiloxytitanium, with butyl alcohol.

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Literature cited

  1. W. D. English, L. H. Sommer, J. Am. Chem. Soc. 77, 170 (1955).

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  2. K. A. Andrianov, A. A. Zhdanov, N. A. Kurasheva, and V. G. Dulova, Proc. Acad. Sci. USSR 112, 1050 (1957).

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Authors and Affiliations

  1. Institute of Heteroorganic Received Compounds of the Academy of Sciences of the USSR, USSR

    K. A. Andrianov & V. G. Dulova

Authors
  1. K. A. Andrianov
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  2. V. G. Dulova
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Andrianov, K.A., Dulova, V.G. Synthesis of some (trimethylsiloxy) titanium compounds. Russ Chem Bull 7, 628–629 (1958). https://doi.org/10.1007/BF01151341

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  • DOI: https://doi.org/10.1007/BF01151341

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