Abstract
Vinylporphyrins containing one vinyl group at the pyrrole or benzene ring and their complexes with Cu2+ and Zn2+ have been obtained by the Wittig reaction. Compounds obtained were characterized by physicochemical methods. X-ray diffraction analysis of 5-(4-vinylphenyl)-10,15,20-triphenylporphyrin has been carried out. It is likely that the inclusion of the vinyl group is accompanied by weak electron effects on the macrocycle. No nonequivalence of N-H bonds is observed in initial macrocycles.
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For Part 43, seeRuss. Chem. Bull., 1995,44, 1062.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1827–1832, September, 1995.
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Kitsenko, N.A., Ishkov, Y.V., Voloshanovskii, I.S. et al. Preparation and reactivity of metal-containing monomers. Russ Chem Bull 44, 1758–1763 (1995). https://doi.org/10.1007/BF01151307
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DOI: https://doi.org/10.1007/BF01151307