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Homolytic addition of polyhaloalkanes to α-vinyloxy-ω-trialkylstannoxy-alkanes as a new route to 2-perhaloalkylmethyl-substituted 1,3-dioxacyclanes

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Abstract

Photoinduced reactions of α-vinyloxy-ω-trialkylstannoxyalkanes, CH2=CHO(CH2) n OSnEt3 (n = 2 to 4), with polyhaloalkanes result in 2-perhaloalkylmethyl-substituted 1,3-dioxacyclanes.

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References

  1. P. V. Arbuzov, V. I. Rakhlin, R. G. Mirskov, B. Z. Shterenberg, and M. G. Voronkov,Metalloorg. Khim., 1989,2, 889 [Organomet. Chem. USSR, 1989,2, 465 (Engl. Transl.)].

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1824–1826, September, 1995.

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Arbuzov, P.V., Voronkov, M.G., Mirskov, R.G. et al. Homolytic addition of polyhaloalkanes to α-vinyloxy-ω-trialkylstannoxy-alkanes as a new route to 2-perhaloalkylmethyl-substituted 1,3-dioxacyclanes. Russ Chem Bull 44, 1755–1757 (1995). https://doi.org/10.1007/BF01151306

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  • DOI: https://doi.org/10.1007/BF01151306

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