Skip to main content
SpringerLink
Log in

Formation and stability of proton-amine-inorganic anion complexes in aqueous solution

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Interaction of some amines with inorganic ligands was studied potentiometrically in aqueous solutions at 25°C at different ionic strengths. The systems taken into account were: meta-PP, meta-TPP, en-PP, en-TPP, en-HPO 2−4 , dap-SO 2−4 , tetren-HPO 2−4 , 6da-PP and 8da-TPP (meta=methylamine, en=ethylenediamine, tetren=tetraethylenepentamine, dap=1,2-diaminopropane, 6da=1,6-hexanediamine, 8da=1,8-octanediamine, PP=pyrophosphate, TPP=tripolyphosphate). Several ALHr species are formed for all the studied mixed systems (A=amine, L =inorganic ligand), and in some cases ApLqHr species were also found. The stability of mixed proton-ligand-ligand species is proportional to the charges involved in the complexation reaction and, to some extent, it depends on steric characteristic of the ligands. A simple relationship has been found between formation constants of mixed ligand species and charges involved in the complexation reaction. The ionic strength dependence of formation constants has been taken into account, and it was found that, also for these types of mixed complexes, a general equation independent of the nature of the reactants can be used.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. G. Daniele, A. De Robertis, C. De Stefano, S. Sammartano, and C. Rigano,J. Chem. Soc. Dalton Trans. 2353 (1985).

  2. A. De Robertis, C. De Stefano, S. Sammartano, and C. Rigano,Talanta 34, 933 (1987).

    Google Scholar 

  3. P. G. Daniele, A. De Robertis, C. De Stefano, A. Gianguzza, and S. Sammartano.J. Chem. Res. (S)300 (1990) (M) 2316 (1990).

    Google Scholar 

  4. P. G. Daniele, A. De Robertis, C. De Stefano, and S. Sammartano,Ann. Chim. (Rome)80, 177 (1990).

    Google Scholar 

  5. A. De Robertis, and C. De Stefano,Talanta 38, 439 (1991).

    Google Scholar 

  6. G. Cuffari, A. De Robertis, C. De Stefano, and C. Foti,J. Chem. Res. (S) 264, (M) 2501 (1991).

    Google Scholar 

  7. A. De Robertis, C. Foti, and A. Gianguzza,Annali di Chimica 83, 485 (1993).

    Google Scholar 

  8. S. Capone, A. Casale, A. Curró, A. De Robertis, C. De Stefano, S. Sammartano, and R. Scarcella,Ann. Chim. (Rome)76, 441 (1986); A. Casale, A. De Robertis, and F. Licastro,Thermochim. Acta 143, 289 (1989).

    Google Scholar 

  9. P. G. Daniele, A. De Robertis, C. De Stefano, and S. Sammartano,J. Solution Chem. 18, 23 (1989).

    Google Scholar 

  10. A. Casale, A. De Robertis, F. Licastro, and C. Rigano,J. Chem. Res. (S) 204, (M) 1601–1620 (1990).

    Google Scholar 

  11. A. De Robertis, C. De Stefano, and G. Patané,Thermochim. Acta 209, 7 (1992).

    Google Scholar 

  12. A. De Robertis, C. De Stefano, G. Patané, and S. Sammartano,J. Solution Chem. 22, 927 (1993).

    Google Scholar 

  13. P. G. Daniele, A. De Robertis, C. De Stefano, D. Gastaldi, and S. Sammartano,Ann. Chim. (Rome),83, 575 (1993).

    Google Scholar 

  14. C. De Stefano, A. Gianguzza, and S. Sammartano,Talanta 40, 629 (1993).

    Google Scholar 

  15. L. Abate, A. De Robertis, and C. Rigano,J. Solution Chem. 22, 339 (1993).

    Google Scholar 

  16. E. Kimura, A. Sakonaka, T. Yatsunami, and M. Kodama,J. Am. Chem. Soc. 103, 3041 (1981).

    Google Scholar 

  17. M. W. Hosseini and J. M. Lenh,J. Am. Chem. Soc. 104, 3535 (1982).

    Google Scholar 

  18. E. Kimura, M. Kodama, and T. Yatsunami,J. Am. Chem. Soc. 104, 3182 (1982).

    Google Scholar 

  19. B. Dietrich, J. M. Lehn, C. Pascard, and E. Sonveaux,Helvetica Chimica Acta 67, 91 (1984).

    Google Scholar 

  20. M. W. Hosseini and J. M. Lehn,Helvetica Chimica Acta 69, 587 (1986).

    Google Scholar 

  21. M. W. Hosseini and J. M. Lehn,Helvetica Chimica Acta 70, 1312 (1987).

    Google Scholar 

  22. I. Labadi, E. Jenei, R. Labti, and H. Lonnberg,Acta Chem. Scand. 45, 1055 (1991).

    Google Scholar 

  23. C. De Stefano, P. Princi, C. Rigano, and S. Sammartano,Ann. Chim. (Rome)77, 643 (1987).

    Google Scholar 

  24. C. De Stefano, P. Mineo, C. Rigano, and S. Sammartano,Ann. Chim. (Rome)83, 243, (1993).

    Google Scholar 

  25. A. Casale, P. G. Daniele, A. De Robertis, and S. Sammartano,Ann. Chim. (Rome)78, 249 (1988).

    Google Scholar 

  26. A. Casale, P. G. Daniele, C. De Stefano, and S. Sammartano,Talanta 36, 903 (1989).

    Google Scholar 

  27. P. G. Daniele, A. De Robertis, C. De Stefano, and S. Sammartano, inMiscellany of Scientific Papers Offered to Enric Casassas, S. Alegret, J. J. Arias, D. Bercelo, J. Casal, G. Rauret, eds. (Universitat Autonoma de Barcelona, Bellaterra, Spain 1991); and references therein.

    Google Scholar 

  28. R. W. Chlebek and M. W. Lister,Can. J. Chem. 44, 437 (1966).

    Google Scholar 

  29. R. M. Smith and A. E. Martell,Amines, Vol. 2: “Critical Stability Constants,” (Plenum Press, London, 1975).

    Google Scholar 

  30. P. G. Daniele, A. De Robertis, C. De Stefano, A. Gianguzza, and S. Sammartano,J. Solution Chem. 20, 495 (1991).

    Google Scholar 

  31. C. De Stefano, C. Rigano, S. Sammartano, and R. Scarcella,J. Chem. Res., (S) 372 (1988).

  32. C. De Stefano, C. Foti, and A. Gianguzza,J. Chem. Res. (S) 464, (M) 2639.

  33. A. Vacca and A. Sabatini, inMetal Complexes in Solution, E. A. Jenne, E. Rizzarelli, V. Romano, and S. Sammartano, eds., (Piccin, Padua, 1986).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dpt. Chimica Analitica, Università, via P. Giuria 5, I-10125, Torino, Italy

    Enrico Prenesti

  2. Dpt. Chimica Inorganica, Analitica e Struttura Molecolare, Università, Salita Sperone 31, I-98166, S. Agata di Messina, Messina, Italy

    Pier G. Daniele, Concetta De Stefano & Silvio Sammartano

Authors
  1. Pier G. Daniele
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Enrico Prenesti
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Concetta De Stefano
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Silvio Sammartano
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Daniele, P.G., Prenesti, E., De Stefano, C. et al. Formation and stability of proton-amine-inorganic anion complexes in aqueous solution. J Solution Chem 24, 325–341 (1995). https://doi.org/10.1007/BF01150872

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01150872

Key Words

Search

Navigation