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Über die Einschiebung von Phenylisocyanat in eine Silicium-Schwefelbindung

Insertion of phenyl isocyanate in a silicon-sulphur bond

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

S-Methyl-N-phenyl-iminothiocarbonic acid-tri-O.O′.O″-isopropylsilicic acid anhydride,1 is obtained from the reaction of phenyl isocyanate and methylthiotriiso-propoxysilan.1 readily hydrolyses forming S-methylthiocarbanilide. Substances are characterized by their mass and1H-NMR spectra.

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Literatur

  1. A. Meller undG. Beer, unveröffentlicht.

  2. Vergleiche:Beilstein, Handbuch der Org. Chem., 4. Aufl.,12, S. 394 (1929).

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  3. Vergleiche:J. W. Emsley, J. Feeney undL. H. Sutcliffe, High Resolution NMR-spectroscopy, Vol.2, S. 1124, 1121. Oxford: Pergamon Press. 1966.

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  4. Vergleiche:Beilstein, Handbuch der Org. Chem., 4. Aufl.,12, S. 386 (1929).

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Beer, G., Meller, A. & Wojnowska, M. Über die Einschiebung von Phenylisocyanat in eine Silicium-Schwefelbindung. Monatshefte für Chemie 106, 567–569 (1975). https://doi.org/10.1007/BF01150539

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  • DOI: https://doi.org/10.1007/BF01150539

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