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Die Schmelzdiagramme der Systeme CsN3/Zn(N3)2 und KN3/Zn(N3)2

Phase diagrams of the systemsCsN 3/Zn(N3)2 andKN 3/Zn(N3)2

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The phase diagrams of the systems CsN3/Zn(N3)2 and KN3/Zn(N3)2 have been obtained employing the microscopic technique ofL. Kofler andA. Kofler. Within the system CsN3/Zn(N3)2 three eutectics at 148°C, 142°C, and 210°C were found. Besides Cs2Zn(N3)4, melting incongruently in the interval 153°C to 170°C, there exist two further compounds of the most probable composition Cs3Zn2(N3)7 and CsZn2(N3)5, melting congruently at 170°C and 210°C, resp. In the system KN3/Zn(N3)2 there exist two eutectics at 203°C and 172°C and two compounds, one of them, i.e. K2Zn(N3)4, melting congruently at 206°C, the other one, with composition KZn3(N3)7 or KZn4(N3)9, melting incongruently at 210°C.

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Literatur

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Authors and Affiliations

  1. Institut für Physikalische und Theoretische Chemie der Technischen Hochschule Graz, Rechbauerstraße 12, A-8010, Graz, Österreich

    Herwig G. Winkler, Hagen T. Spath &  Karl Torkar

Authors
  1. Herwig G. Winkler
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  2. Hagen T. Spath
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  3. Karl Torkar
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Herrn Professor Dr.Heribert Grubitsch zum 70. Geburtstag gewidmet.

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Winkler, H.G., Spath, H.T. & Torkar, K. Die Schmelzdiagramme der Systeme CsN3/Zn(N3)2 und KN3/Zn(N3)2 . Monatshefte für Chemie 106, 535–545 (1975). https://doi.org/10.1007/BF01150535

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  • DOI: https://doi.org/10.1007/BF01150535

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