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Darstllung und Eigenschaften von Cyclopentasilan

Preparation and properties of cyclopentasilane

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The first known cyclosilane Si5H10 is yielded by the reaction of Si5Br10 with LiAlH4. The cyclic Si5Br10 results at the reaction of the known Si5 ph 10 with HBr and is the first known representative of the class of cyclic silicon bromides too. Si5H10 and Si5Br10 are characterized and their properties are described. A detailed mass spectroscopic investigation shown an interesting fragmentation into Si +5 -particle.

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Authors and Affiliations

  1. Aus dem Institut für Anorganische Chemie der Technischen Hochschule in Graz, Rechbauerstraße 12, A-8010, Graz, Österreich

    Edwin Hengge & Günther Bauer

Authors
  1. Edwin Hengge
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  2. Günther Bauer
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Mit 1 Abbildung

Teilauszug aus der DissertationG. Bauer, Technische Hochschule in Graz 1975.

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Hengge, E., Bauer, G. Darstllung und Eigenschaften von Cyclopentasilan. Monatshefte für Chemie 106, 503–512 (1975). https://doi.org/10.1007/BF01150532

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  • DOI: https://doi.org/10.1007/BF01150532

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