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Tetramethylammonium-fluoroaluminate,-gallate und-indate

Fluoro metallates (III), VIII: Tetramethylammonium-fluoroaluminates,-gallates, and-indates

Untersuchungen über Fluoro-metallate(III), 8. Mitt.

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Four new compounds have been isolated from the systemMF3−(CH3)4NF−HF−H2O (M=Al, Ga, In) and investigated by thermal analysis and IR spectroscopy. Tetrahedral coordination of Al(III) in (CH3)4NAlF4 seems most probable. This compound, the first known greater thermal stability than other dehydrates. IR spectra of all the other compounds may be interpreted on the basis of a distorted octahedral coordination.

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Authors and Affiliations

  1. Aus dem Laboratorium für Anorganische Chemie, Universität Ljubljana, Jugoslawien

    Peter Bukovec & Jože Šiftar

  2. Institut “Jožef Stefan”, Universität Ljubljana, Murnikova 6, YU-61001, Ljubljana, Jugoslawien

    Peter Bukovec & Jože Šiftar

Authors
  1. Peter Bukovec
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  2. Jože Šiftar
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Additional information

7. Mitt: Mh. Chem.105, 1299 (1974).

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Bukovec, P., Šiftar, J. Tetramethylammonium-fluoroaluminate,-gallate und-indate. Monatshefte für Chemie 106, 483–490 (1975). https://doi.org/10.1007/BF01150529

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  • DOI: https://doi.org/10.1007/BF01150529

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