Skip to main content
SpringerLink
Log in

Die Bildungsenthalpie von Zinndijodid, SnJ2 (c)

The heat of formation of tin diiodide,SnJ 2 (c)

  • Anorganische, Struktur- und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The heat of reaction for SnJ2 (c)+J2 (c)+4045 CS2 (l)=[SnJ4; 4045 CS2] (sol) has been determined to be (−41.12±0.55) kJ mol−1, [(−9.83±0.13) kcal mol−1] by isoperibol solution calorimetry. Combining this result with the heat of formation of SnJ4 in CS2 determined in a previous investigation11 the value (−153.9±1.40) kJ mol−1, [(−36.9±0.33) kcal mol−1] has been derived for the heat of formation, ΔH f ι (SnJ2;c; 298.15 K), of tin diiodide.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. Landolt-Börnstein, Zahlenwerte aus Physik, Chemie, Astronomie, Geophysik, Technik; 6. Aufl., Bd. II/4: Kalorische Zustandsgrößen. Berlin-Göttingen-Heidelberg: Springer. 1961.

    Google Scholar 

  2. O. Kubaschewski, E. Ll. Evans undC. B. Alcock, Metallurgical Thermochemistry, 4. Aufl. Oxford-London-Edinburgh-New York-Toronto-Sydney-Paris-Braunschweig: Pergamon Press. 1967.

    Google Scholar 

  3. D. D. Wagman, W. H. Evans, V. B. Parker, I. Halow, S. M. Bailey undR. H. Schumm, Selected Values of Chemical Thermodynamic Properties, NBS Technical Note 270-3, Washington (D.C.) 1968.

  4. F. D. Rossini, D. D. Wagman, W. H. Evans, S. Levine undE. Jaffe, Selected Values of Chemical Thermodynamic Properties, NBS Circular 500, Washington (D.C.) 1952.

  5. M. Berthelot, Ann. chim. phys. [5]15, 185 (1878).

    Google Scholar 

  6. F. R. Bichowsky undF. D. Rossini, The Thermochemistry of the Chemical Substances. New York: Reinhold. 1936. (Second Printing 1948).

    Google Scholar 

  7. W. Biltz undW. Fischer, Z. anorg. allg. Chem.129, 1 (1923).

    Google Scholar 

  8. P. Freundler undY. Laurent, Bull. Soc. chim. France [4]37, 1133 (1925).

    Google Scholar 

  9. Lit.6, S. 6 1936. (Second Printing 1948).

    Google Scholar 

  10. Landolt-Börnstein, Physikalisch-chemische Tabellen, 5. Aufl., Berlin: Springer. 1923, 1927 (1. Erg.-Bd.); 1931 (2. Erg.-Bd.); 1936 (3. Erg.-Bd.).

    Google Scholar 

  11. J. Mikler, Mh. Chem.104, 376 (1973).

    Google Scholar 

  12. L. Vanino, Handbuch der Präparativen Chemie, Bd. I., S. 480. Stuttgart: Enke. 1913.

    Google Scholar 

  13. G. Brauer, Handbuch der Präparativen Anorganischen Chemie, 2. Aufl., I. Bd., S. 651. Stuttgart: Enke. 1960.

    Google Scholar 

  14. Cv. Bontschev, D. Christov undB. Manuschev, Z. anorg. allg. Chem.379, 95 (1970).

    Google Scholar 

  15. H. S. van Klooster, Z. anorg. allg. Chem.79, 223 (1913).

    Google Scholar 

  16. W. Reinders undS. de Lange, Z. anorg. allg. Chem.79, 230 (1913).

    Google Scholar 

  17. A. Kabesh undR. S. Nyholm, J. Chem. Soc. [London]1951, 3245.

  18. T. N. Sevast'yanova undN. V. Karpenko, J. Fiz. Khim. [russ.]45, 1834 (1971).

    Google Scholar 

  19. J. Mikler undE. Bauernfeind, Mh. Chem.103, 116 (1972).

    Google Scholar 

  20. S. R. Gunn, J. Chem. Thermodyn.3, 19 (1971).

    Google Scholar 

  21. F. D. Rossini inF. D. Rossini (Hrsg.), Experimental Thermochemistry, Vol. I, S. 319. New York: Interscience. 1956. (Second printing 1965.)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Anorganische Chemie der Universität Wien, Währinger Straße 42, A-1090, Wien, Österreich

    Johann Mikler & Alfred Janitsch

Authors
  1. Johann Mikler
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Alfred Janitsch
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mikler, J., Janitsch, A. Die Bildungsenthalpie von Zinndijodid, SnJ2 (c). Monatshefte für Chemie 106, 399–406 (1975). https://doi.org/10.1007/BF01150520

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01150520

Search

Navigation