Abstract
An investigation has been carried out on the feasibility of employing a CaO-MgO-Al2O3-SiO2 glass-ceramic (known as Silceram) as a matrix for a fibre composite produced by a powder route. Some important properties of the parent glass, e.g. surface energy, viscosity, have been measured as well as the kinetics and structural aspects of the sintering and crystallization processes. It was found that the crystallization of the main phase, diopside, occurred from the surface of individual particles and internally with activation energies of 392 to 452 kJ mol−1 and 258 to 323 kJ mol−1 respectively. However, the surface crystallization was only dominant when the glass powder was fine (<38μm). The work has demonstrated that this glass-ceramic shows promise as the matrix component of a composite because
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(i)
both sintering and crystallization may be achieved by a single stage heat treatment at relatively low temperatures of 900° C to 1000° C, because the glass powder can be compressed and sintered by viscous flow before crystallization commences, and
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(ii)
the resulting microstructure is fine, and in the case of the hot-pressed material there is negligible porosity.
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References
P. S. Rogers, J. Williamson, J. F. Bell andM. Campbell, in “Energy Conservation in Industry — Applications and Techniques”, edited by A. S. Strub and H. Ehringer (VDI, Verlag, Dusseldorf, 1984) p. 280.
S. Carter, C. B. Ponton, R. D. Rawlings andP. S. Rogers,J. Mater Sci. 23 (1988) 2622.
C. B. Ponton, R. D. Rawlings andP.S. Rogers, in “Proceedings of the Conference on Special Ceramics” (The Inst. Ceramics, London, December 1986) p. 229.
ASTM C338-73, part 17 (1975) 287.
P. W. Mcmillan, in “Glass-Ceramics” 2nd edn. (Academic Press, London, 1979).
W. Vogel, in “Chemistry of Glass” (The American Ceramic Society, Ohio, 1985) p. 22.
F. Bashforth andJ. C. Adams, in “An attempt to Test Theories of Capillarity” (Cambridge University Press, Cambridge, 1883).
C. T. Moynihan, A. J. Easteal andJ. Wilder,J. Phys. Chem. 78 (1974) 2673.
M. Campbell, Internal Report, Imperial College (1983).
A. Marotta, S. Saiello andA. Buri,J. Noncryst. Solids 57 (1983) 473.
H. Kissinger,Anal. Chem. 29 (1957) 1702.
J. A. Augis andJ. D. Bennett,J. Thermal Anal. 13 (2) (1978) 283.
R. J. Kirkpatrick,Amer. J. Sci. 274 (1974) 215.
L. Klein andD. R. Uhlmann,J. Geophys. Res. 79 (1974) 4869.
L. R. Barrett andA. G. Thomas,J. Soc. Glass. Technol. 43 (1959) 179.
M. L. Williams, R. F. Landel andJ. D. Ferry,J. Amer. Chem. Soc. 77 (1955) 3701.
G. Adam andJ. H. Gibbs,J. Chem. Phys. 43 (1965) 139.
I. Gutzow,Contemp. Phys. 21 (1980) 121.
J. Williamson, A. J. Tipple andP. S. Rogers,J. Iron and Steel Inst. 206 (1968) 898.
S. Carter, Internal report, Imperial College (1986).
W. D. Kingery, H. K. Bowen andD. R. Uhlmann, in “Introduction to Ceramics” (Wiley, Chichester, 1976) p. 604.
P. S. Turner,J. Res. NBS 37 (1946) 239.
R. S. Carmichael, in “Handbook of Physical Properties of Rocks, Vol. III” (CRC Press, Cleveland, 1984) p. 102.
D. G. Holloway, in “The Physical Properties of Glass” (Wykeham Pub., London, 1973) p. 128.
G. R. Rigby andA. T. Green,Trans. Brit. Ceram. Soc. 41 (1942) 123.
L. J. Shelestak, R. A. Chavez andJ. D. Mackenzie,J. Non-Cryst. Solids 27 (1978) 75.
K. Matusita, S. Sakka andY. Matsui,J. Mater. Sci. 10 (1975) 961.
Nippon Carbon Co. “Nicalon data sheet” (Japan, 1985).
“Ceramic Glossary 1984”, edited by W. W. Perkins (The American Ceramic Society, 1984) p. 52.
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Kim, H.S., Rawlings, R.D. & Rogers, P.S. Sintering and crystallization phenomena in Silceram glass. J Mater Sci 24, 1025–1037 (1989). https://doi.org/10.1007/BF01148794
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DOI: https://doi.org/10.1007/BF01148794