Conclusions
-
1.
The aryl acetate conformations show a planar ester group, and cis-oriented C=0 and C-0 bonds, the aryl radical being rotated out of the bond plane by 65°.
-
2.
In the trifluoroacetates, the aryl radical rotation has diminished to 25°.
-
3.
The dipole moments of the ester oxygen atom bonds are not additive in the acetates and their analogs.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1336–1339, June, 1977.
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Arbuzov, B.A., Timosheva, A.P., Vul'fson, S.G. et al. Dipole moments, Kerr constants, and spatial structures of certain phenol esters. Russ Chem Bull 26, 1234–1238 (1977). https://doi.org/10.1007/BF01143908
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DOI: https://doi.org/10.1007/BF01143908