Conclusions
-
1.
Study has been made of the structures of protonated
and methylated
salts of trimethylphosphine oxide.
-
2.
The protonated salts have mesomorphic structures with positive charge distribution in the POH+ group; the methylated salts show purely phosphonium structures,
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For Communication 10 see [1].
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1313–1318, June, 1977.
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Matrosov, E.I., Komarova, M.I. & Kabachnik, M.I. The acid-base properties of phosphorus compounds. 11. Calculation of the structures and vibration frequencies of the (CH3)3POH+ and (CH3)3POCH3 + ions. Russ Chem Bull 26, 1211–1215 (1977). https://doi.org/10.1007/BF01143903
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DOI: https://doi.org/10.1007/BF01143903