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Effect of high pressure on hydrogen abstraction by the cumyloxy radical

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A quantitative dependence was found for the volumetric activation effect on the reactivity of cumene, n-nonane, toluene, and tert-butylbenzene for hydrogen atom transfer to the cumyloxy radical.

  2. 2.

    The analogous reaction of the cumyloxy radical with anisole does not obey this relationship since the reactivity of anisole is apparently a function not only of the C-H bond dissociation energy but also polar factors.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. M. Zhulin, O. B. Rudakov & G. A. Stashina

Authors
  1. V. M. Zhulin
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  2. O. B. Rudakov
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  3. G. A. Stashina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1205–1208, May, 1985.

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Zhulin, V.M., Rudakov, O.B. & Stashina, G.A. Effect of high pressure on hydrogen abstraction by the cumyloxy radical. Russ Chem Bull 34, 1104–1107 (1985). https://doi.org/10.1007/BF01142815

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  • DOI: https://doi.org/10.1007/BF01142815

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