Conclusions
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1.
Copper salts of dialkylthiophosphoric acids react with propargyl halides to form O,O-dialkyl-S-propargyl thiophosphates.
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2.
Sterically hindered propargyl halides readily react with cuprous dialkylthiophosphates hut do not react with the analogous potassium salts.
Literature cited
L. A. Vikhreva, T. A. Pudova, K. K. Babasheva, A. M. Darisheva, E. I. Matrosov, N. N. Godovikov, and M. I. Kabachnik, Dokl. Akad. Nauk SSSR,274, 822 (1984).
G. Shrader, Chem. Zbl., 6971 (1960).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1181–1183, May, 1985.
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Vikhreva, L.A., Pudova, T.A., Godovikov, N.N. et al. Reactions of copper salts of dialkylthiophosphoric acids with propargyl halides. Russ Chem Bull 34, 1080–1082 (1985). https://doi.org/10.1007/BF01142806
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DOI: https://doi.org/10.1007/BF01142806