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Synthesis of derivatives of homo- and heteropolyuronides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We carried out stereospecific polycondensations of triphenylmethyl ethers of 1,2-O-cyanoethylidene derivatives of D-glucuronic and pseudobiouronic acids.

  2. 2.

    We found that the polycondensation products of triphenylmethyl ethers of 1,2-O-cyanoethylidene derivatives of sugars do not contain the triphenylmethyl groups, whereupon the rate of removal of the trityl group is determined by the nature of the monomer.

  3. 3.

    We have proposed an appropriate method for estimating the average length of chain of the polycondensation products.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. I. Betaneli, M. M. Litvak, L. V. Bakinovskii & N. K. Kochetkov

Authors
  1. V. I. Betaneli
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  2. M. M. Litvak
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  3. L. V. Bakinovskii
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  4. N. K. Kochetkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1172–1177, May, 1985.

The authors thank M. I. Struckhov, V. S. Bogdanov, A. I. Lutsenko, and A. S. Shashkov for plotting the PMR and13C NMR spectra and aid in their interpretation.

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Betaneli, V.I., Litvak, M.M., Bakinovskii, L.V. et al. Synthesis of derivatives of homo- and heteropolyuronides. Russ Chem Bull 34, 1072–1077 (1985). https://doi.org/10.1007/BF01142804

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  • DOI: https://doi.org/10.1007/BF01142804

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