Conclusions
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1.
An effective scheme of synthesis of 1,6-anhydro-2-desoxy-2-C-methyl-3-O-benzyl-4-methylene-β-D-xylohexapyranose, an important intermediate compound in the synthesis of macrolide antibiotics, has been developed.
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2.
A C9-C13 fragment of erythronolide A was synthesized in 14 stages from levoglucosan to give an overall yield of 7.5%.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1161–1166, May, 1985.
For Communication see [7].
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Sviridov, A.F., Ermolenko, M.S., Yashunskii, D.V. et al. Synthesis of macrolide antibiotics Communication 7. New synthesis of C9-C13 fragment of erythronolide A. Russ Chem Bull 34, 1060–1065 (1985). https://doi.org/10.1007/BF01142802
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DOI: https://doi.org/10.1007/BF01142802