Conclusions
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1.
A rearrangement was discovered of 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-4-O-mesyl-β-D-glactopyranose into 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose.
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2.
The C13-epi-C9-C13 fragment of erythronolide A was synthesized from levoglucosan in 18 stages in an overall yield of 3.4%.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1157–1161, May, 1985.
For Communication 5, see [1].
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Sviridov, A.F., Ermolenko, M.S., Yashunskii, D.V. et al. Synthesis of macrolide antibiotics. Communication 6. Synthesis of C13-EPI-C9-C13 fragment of erythronolide a. Russ Chem Bull 34, 1056–1060 (1985). https://doi.org/10.1007/BF01142801
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DOI: https://doi.org/10.1007/BF01142801