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Synthesis of the principal chain of the o-antigenic polysaccharides ofShigella flexneri. Communicaton 5. Synthesis of o-(4,6-di-o-benzoyl-2-desoxy-2-phthalimido-β-D-glucopyranosyl)-(1 → 2)-o-(3,4-di-o-benzoyl-α-L-rhamnopyranosyl)-(1 → 2)-o-(3,4-di-o-benzoyl-α-L-rhamnopyransoyl)-(1→ 3)-4-o-benzoyl-1,2-o-[1-(exocyano)ethylidene]-β-L-rhamnopyranose, a monomer precursor for polycondensation

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Conventional derivatives of L-rhamnose and D-glucosamine have been employed in the stepwise and block synthesis of a functionalized tetrasaccharide repeating unit of the O-anti-genic polysaccharide ofSh. flexneri. This is a precursor of the monomer for polycondensation.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    N. É. Bairamova, Yu. E. Tsvetkov, L. V. Bakinovskii & N. K. Kochetkov

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  1. N. É. Bairamova
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  2. Yu. E. Tsvetkov
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  3. L. V. Bakinovskii
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  4. N. K. Kochetkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1145–1150, May, 1985.

For Communication 4, see [1].

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Bairamova, N.É., Tsvetkov, Y.E., Bakinovskii, L.V. et al. Synthesis of the principal chain of the o-antigenic polysaccharides ofShigella flexneri. Communicaton 5. Synthesis of o-(4,6-di-o-benzoyl-2-desoxy-2-phthalimido-β-D-glucopyranosyl)-(1 → 2)-o-(3,4-di-o-benzoyl-α-L-rhamnopyranosyl)-(1 → 2)-o-(3,4-di-o-benzoyl-α-L-rhamnopyransoyl)-(1→ 3)-4-o-benzoyl-1,2-o-[1-(exocyano)ethylidene]-β-L-rhamnopyranose, a monomer precursor for polycondensation. Russ Chem Bull 34, 1046–1051 (1985). https://doi.org/10.1007/BF01142799

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  • DOI: https://doi.org/10.1007/BF01142799

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