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Synthesis of the principal chain of the o-antigenic polysaccharides ofShigella flexneri. Communication 4. Synthesis of 1,3-di-o-acetyl-4,6-di-o-benzoyl-2-desoxy-2-phthalimido-D-glucopyranose and 1-o-acetyl-2-o-(3-o-acetyl-4,6-di-o-benzoyl-2-desoxy-2-phthalimido-β-D-glucopyranosyl)-3,4-di-o-benzoyl-L-rhamnopyranose

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Methyl-3-O-acetyl-4,6-di-O-benzoyl-2-desoxy-2-phthalimido-β-D-glucopyranoside and 1,3-di-O-acetyl-4,6-di-O-benzoyl-2-desoxy-2-phthalimido-D-glucopyranose have been obtained. These are conventional derivatives for the introduction of the 3-substituted 2-desoxy-2-amino-β-D-glucopyranose residue in oligosaccharide synthesis.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1140–1145, May, 1985.

For Communication 3, see [1].

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Bairamova, N.É., Bakinovskii, L.V. & Kochetkov, N.K. Synthesis of the principal chain of the o-antigenic polysaccharides ofShigella flexneri. Communication 4. Synthesis of 1,3-di-o-acetyl-4,6-di-o-benzoyl-2-desoxy-2-phthalimido-D-glucopyranose and 1-o-acetyl-2-o-(3-o-acetyl-4,6-di-o-benzoyl-2-desoxy-2-phthalimido-β-D-glucopyranosyl)-3,4-di-o-benzoyl-L-rhamnopyranose. Russ Chem Bull 34, 1041–1046 (1985). https://doi.org/10.1007/BF01142798

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  • DOI: https://doi.org/10.1007/BF01142798

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