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Synthesis of the principal chain of the o-antigenic polysaccharides ofShigella flexneri. Communication 3. Synthesis of 4-o-benzoyl-3-o-(2-o-acetyl-3,4-di-o-benzoyl-α-L-rhamnopyranosyl)-1,2-o-[1-(exocyano)· ethyliden]-β-L-rhamnopyranose

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    O-α-L-Rhamnopyranosyl-1,2-O-cyanoethylidene-β-L-rhamnopyranoses have been synthesized by glycosylation of 1,2-O-cyanoethylidene-β-L-rhamnopyranose deriviatives.

  2. 2.

    The synthesis has been effected of a functionalized disaccharide for the construction of the tetrasaccharide monomer and its polycendensation in order to obtain the O-antigenic polysaccharide of the bacteriumSh. flexneri.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    N. É. Bairamova, L. V. Bakinovskii & N. K. Kochetkov

Authors
  1. N. É. Bairamova
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  2. L. V. Bakinovskii
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  3. N. K. Kochetkov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1134–1139, May, 1985.

For Communication 2, see [1].

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Bairamova, N.É., Bakinovskii, L.V. & Kochetkov, N.K. Synthesis of the principal chain of the o-antigenic polysaccharides ofShigella flexneri. Communication 3. Synthesis of 4-o-benzoyl-3-o-(2-o-acetyl-3,4-di-o-benzoyl-α-L-rhamnopyranosyl)-1,2-o-[1-(exocyano)· ethyliden]-β-L-rhamnopyranose. Russ Chem Bull 34, 1036–1041 (1985). https://doi.org/10.1007/BF01142797

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  • DOI: https://doi.org/10.1007/BF01142797

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