Conclusions
1,2-O-Cyanoethylidene derivatives of rhamnopyranose with a free hydroxyl group in the 3 position and with readily removable protect at O3 have been synthesized. These are synthons for oligosaccharide synthesis.
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For Communication 1, cf. [1].
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1129–1134, May, 1985.
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Bairamova, N.É., Ovchinnikov, M.V., Bakinovskii, L.V. et al. Synthesis of the principal chain of the o-antigenic polysaccharides ofShigella flexneri. Communication 2. Synthesis of 4-o-benzoyl-1,2-o-(1-(cyanoethylidene)-β-L-rhamnopyranose. Russ Chem Bull 34, 1031–1035 (1985). https://doi.org/10.1007/BF01142796
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DOI: https://doi.org/10.1007/BF01142796