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Synthesis of the principal chain of the 0-antigenic polysaccharides ofShigella flexneri Communication 1. Synthesis of 2,4- and 3,4-di-o-benzoyl-α-L-rhamnopyranosides by a combination of selective acylation and deacetylation, and the synthesis of 1,2-di-o-acetyl-3,4-di-o-benzoyl-L-rhamnopyranose via 1,2-o-benzylidene-3,4-di-o-benzoyl-β-L-rhamnopyranose

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Some derivatives of L-rhamnopyranose have been obtained which contain easily-removed O2 or O3 protection. These are synthons for oligosaccharide synthesis.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    N. É. Bairamova, L. V. Bakinovskii & N. K. Kochetkov

Authors
  1. N. É. Bairamova
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  2. L. V. Bakinovskii
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  3. N. K. Kochetkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1122–1128, May, 1985.

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Bairamova, N.É., Bakinovskii, L.V. & Kochetkov, N.K. Synthesis of the principal chain of the 0-antigenic polysaccharides ofShigella flexneri Communication 1. Synthesis of 2,4- and 3,4-di-o-benzoyl-α-L-rhamnopyranosides by a combination of selective acylation and deacetylation, and the synthesis of 1,2-di-o-acetyl-3,4-di-o-benzoyl-L-rhamnopyranose via 1,2-o-benzylidene-3,4-di-o-benzoyl-β-L-rhamnopyranose. Russ Chem Bull 34, 1024–1030 (1985). https://doi.org/10.1007/BF01142795

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  • DOI: https://doi.org/10.1007/BF01142795

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