Conclusions
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1.
A new reaction was found for cyclic fluoroolefins with hydrazines leading to hydrazones of alicyclic perketones. Thus, perfluorocyclobutene and 1,2-dichlorohexafluorocyclopentene gave cyclobutanetetraone tetrakishydrazone and cyclopentanepentaone pentakishydrazone, respectively.
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2.
An x-ray diffraction structural analysis showed that cyclobutanetetraone tetrakishydrazone exists exclusively in the tetrakishydrazone form.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No, 5, pp. 1097–1101, May, 1985.
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Knunyants, I.L., Struchkov, Y.T., Bargamova, M.D. et al. Synthesis of cyclic polyketone polyhydrazones and the x-ray diffraction study of cyclobutanetetraone tetrakishydrazone. Russ Chem Bull 34, 1001–1005 (1985). https://doi.org/10.1007/BF01142790
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DOI: https://doi.org/10.1007/BF01142790