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Structure of iminobis(methylphosphonic) and cyclohexyliminobis(methylphosphonic) acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    X-ray diffraction structural analysis provided the crystal structures of iminobis(methylphosphonic) and cyclohexyliminobis(methylphosphonic) acids and showed that the introduction of the cyclohexyl substituent into the iminobls (methylphosphonic) acid molecule prevents formation of a three-dimensional hydrogen bond system.

  2. 2.

    The phosphonic acid group is capable of performing the function of two carboxylic acid groups in the formation of intermolecular hydrogen bonds.

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Literature cited

  1. L. M. Shkol'nikova, M. A. Porai-Koshits, N. M. Dyatlova, G. F. Yaroshenko, M. V. Rudomino, and E. K. Kozlova, Zh. Strukt. Khim.,23, No. 5, 98 (1982).

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  2. L. M. Shkol'nikova, G. V. Polyanchuk, N. M. Dyatlova, and I. A. Polyakova, Zh. Strukt. Khim.,25, No. 2, 103 (1984).

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  3. F. I. Bel'skii, I. B. Goryunova, P. V. Petrovskii, T. Ya. Medved', and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 103 (1982).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. M. Shkol'nikova, G. V. Polyanchuk, N. M. Dyatlova, T. Ya. Medved', I. B. Goryunova & M. I. Kabachnik

  2. All-Union Scientific-Research Institute for Chemical Reagents and Ultrapure Chemical Compounds, Moscow

    L. M. Shkol'nikova, G. V. Polyanchuk, N. M. Dyatlova, T. Ya. Medved', I. B. Goryunova & M. I. Kabachnik

Authors
  1. L. M. Shkol'nikova
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  2. G. V. Polyanchuk
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  3. N. M. Dyatlova
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  4. T. Ya. Medved'
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  5. I. B. Goryunova
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  6. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1035–1041, May, 1985.

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Shkol'nikova, L.M., Polyanchuk, G.V., Dyatlova, N.M. et al. Structure of iminobis(methylphosphonic) and cyclohexyliminobis(methylphosphonic) acids. Russ Chem Bull 34, 941–947 (1985). https://doi.org/10.1007/BF01142780

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  • DOI: https://doi.org/10.1007/BF01142780

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