Conclusions
In the example of 1,2-shifts of various migrants (Rm) in 1-Rm-2-hydroxy-1,3,4,5,6-penta-methylbenzenonium ions, it has been demonstrated that a quantitative description can be given for nondegenerate carbocation rearrangements within the framework of an approach that has been formulated previously for degenerate rearrangements of arenonium ions. In the example, of carbocations of the acenaphthene series, it has been established that this approach is also applicable to carbocations of a different structural type.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 998–1002, May, 1985.
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Borodkin, G.I., Shubin, V.G. Certain structural-kinetic relationships in rearrangements of “long-lived” carbocations. Russ Chem Bull 34, 908–912 (1985). https://doi.org/10.1007/BF01142773
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DOI: https://doi.org/10.1007/BF01142773