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Hydrogenation of stable iminoxyl radicals in the presence of a complex palladium catalyst with nitrogen-containing ligands

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The hydrogenation of stable iminoxyl radicals in the presence of a complex Pd catalyst, containing a tertiary amine as the ligand, proceeds selectively with the formation of dihydroxylamines.

  2. 2.

    The activity of the biradical isomers of the phthalic acids in the hydrogenation reaction decreases in the order: ortho > meta > para.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1159–1161, May, 1984.

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Saptova, K.A., Cherkashin, G.M., Shuikina, L.P. et al. Hydrogenation of stable iminoxyl radicals in the presence of a complex palladium catalyst with nitrogen-containing ligands. Russ Chem Bull 33, 1064–1066 (1984). https://doi.org/10.1007/BF01141726

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  • DOI: https://doi.org/10.1007/BF01141726

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