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Synthesis of hexaalkyl(aryl)distannanes and their reaction with organic halides under conditions of catalysis by palladium complexes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A convenient method has been developed for the synthesis of hexaalkyl- and hexaaryl-distannanes by the dehydrogenation of R3SnH in the presence of catalytic amounts of Pd complexes.

  2. 2.

    The reaction of hexaalkyldistannanes with organic halides has been studied under conditions of catalysis with Pd complexes. A method has been developed for the synthesis of aryltrialkylstannanes with active electron-accepting substituents in the aromatic ring.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    N. A. Bumagin, Yu. V. Gulevich & I. P. Beletskaya

  2. L. Ya. Karpov Institute of Physical Chemistry, Moscow

    N. A. Bumagin, Yu. V. Gulevich & I. P. Beletskaya

Authors
  1. N. A. Bumagin
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  2. Yu. V. Gulevich
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  3. I. P. Beletskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1137–1142, May, 1984.

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Bumagin, N.A., Gulevich, Y.V. & Beletskaya, I.P. Synthesis of hexaalkyl(aryl)distannanes and their reaction with organic halides under conditions of catalysis by palladium complexes. Russ Chem Bull 33, 1044–1049 (1984). https://doi.org/10.1007/BF01141722

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  • DOI: https://doi.org/10.1007/BF01141722

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