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Fluorine-containing imines

Communication 3. Oxidation of dimethylbenzylamine into aminocarbene by hexafluoroacetone benzoylimine

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In light, hexafluoroacetone benzoylimine oxidizes dimethyIbenzylamine into the corresponding aminocarbene, which adds to benzoylimine to form 2-phenyl-4,4-bis(trifluoromethyl)-5-N-methylbenzylamino-2-oxazoline.

  2. 2.

    In polar media 2-phenyl-4,4-bis(trifluoromethyl)-5-hydroxy-2-oxazoline is present in an equilibrium with an open aldehyde form.

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Authors and Affiliations

  1. A. N. Nesemyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. P. Gambaryan, G. S. Kaitmazova, É. M. Kagramanova, L. A. Simonyan & Z. V. Safronova

Authors
  1. N. P. Gambaryan
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  2. G. S. Kaitmazova
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  3. É. M. Kagramanova
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  4. L. A. Simonyan
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  5. Z. V. Safronova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1102–1105, May, 1984.

For Communication 2, see [1].

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Gambaryan, N.P., Kaitmazova, G.S., Kagramanova, É.M. et al. Fluorine-containing imines. Russ Chem Bull 33, 1012–1016 (1984). https://doi.org/10.1007/BF01141715

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  • DOI: https://doi.org/10.1007/BF01141715

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