Conclusions
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1.
The reactions of 2,4-dinitrochlorobenzene with n-butylamine and tert-butylamine were studied at pressures from atmospheric to 2000 kg/cm2.
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2.
Within this range of pressures, the rate constant of the reaction with n-butylamine more than triples, while the rate constant of the more sterically hindered reaction with tert-buty lamine increases seven- and-a-half-fold.
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Literature cited
K. R. Brower, J. Amer. Chem. Soc.,80, 2105 (1958);81, 3504 (1959).
M. G. Gonikberg, Zh. Fiz. Khimii,37, No. 3, 477 (1963).
J. J. Blanksma and H. H. Schreinemachers, Rec. Trav. chim.52, 428 (1933).
O. L. Brady and F. R. Cropper, J. Chem. Soc.,1950, 507.
Syntheses of Organic Preparations [in Russian], Collection 4, p. 105 (1953).
M. G. Gonikberg, N. I. Prokhorova, and E. F. Litvin, Dokl. AN SSSR,148, 105 (1963).
P. W. Bridgman, Proc. Amer. Acad. Arts and Sci.,49, 3 (1913).
M. G. Gonikberg and A. I. Kitaigorodskii, Dokl. AN SSSR,122, 231 (1958).
M. G. Gonikberg and B. S. Él'yanov, Dokl. AN SSSR,138, 1103 (1961).
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Translated from Izvestiya Akademii Nauk SSSR, Setiya Khimicheskaya, No. 6, pp. 1110–1112, June, 1964
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Gonikberg, M.G., Prokhorova, N.I. Influence of pressure on the rate of nucleophilic aromatic substitution. Russ Chem Bull 13, 1028–1030 (1964). https://doi.org/10.1007/BF01141663
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DOI: https://doi.org/10.1007/BF01141663