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On the mechanism of the oxidation of cyclohexanone

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The parallel formation of hydroperoxide, lactone, and acids in the initial period of the initiated oxidation of cyclohexanone was established. The reaction RO2 + cyclohexanone → RO+lactone, RO → acid, explaining this fact, was proposed.

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Literature cited

  1. W. Pritzkow, Ber.87, 1668 (1954).

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  2. E. T. Denisov and L. N. Denisova, Izv. AN SSSR. Otd. Khim. N.,1963, 1731.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, USSR

    E. T. Denisov & L. N. Denisova

Authors
  1. E. T. Denisov
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  2. L. N. Denisova
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Translated from Izvestiya Akademii Nauk SSSR, Setiya Khimicheskaya, No. 6, pp. 1108–1110, June, 1964

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Denisov, E.T., Denisova, L.N. On the mechanism of the oxidation of cyclohexanone. Russ Chem Bull 13, 1025–1027 (1964). https://doi.org/10.1007/BF01141662

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  • DOI: https://doi.org/10.1007/BF01141662

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