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Chemical investigation of schizandra chinensis Communication 4. Isolation, structure, and synthesis of deoxyschizandrin, and the structure of γ-schizandrin

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    From the unhydrolyzable part of the seed oil ofSchizandra chinensis two new substances were isolated: deoxyschizandrin and pseudo-γ-schizandrin.

  2. 2.

    The structures of deoxyschizandrin andγ-schizandrin were established; they belong to a new group of natural substances derived from 5,6,7,8-tetrahydrodibenzo[a, c] cyclooctene. The structure of deoxyschizandrin was confirmed by the total synthesis of its racemate.

  3. 3.

    The stereochemistry of deoxyschizandrin, γ-schizandrin, and pseudo-γ-schizandrin is discussed.

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Authors and Affiliations

  1. Institute for the Chemistry of Natural Products, Academy of Sciences, USSR

    N. K. Kochetkov, A. Ya. Khorlin & O. S. Chizhov

Authors
  1. N. K. Kochetkov
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  2. A. Ya. Khorlin
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  3. O. S. Chizhov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Setiya Khimicheskaya, No. 6, pp. 1036–1042, June, 1964

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Kochetkov, N.K., Khorlin, A.Y. & Chizhov, O.S. Chemical investigation of schizandra chinensis Communication 4. Isolation, structure, and synthesis of deoxyschizandrin, and the structure of γ-schizandrin. Russ Chem Bull 13, 963–968 (1964). https://doi.org/10.1007/BF01141648

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  • DOI: https://doi.org/10.1007/BF01141648

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