Abstract
A theoretical analysis is presented for the properties of iron-group ions in layer silicates. The most suitable probe for examining AlO6 → AlO4 transitions is CO2+, whose electronic structure makes it capable of reflecting the symmetry of the predominant AlO6 or AlO4 elements in layer silicates.
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, No. 2, pp. 240–244, March–April, 1989.
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Pustovit, A.V., Tarasevich, Y.I. & Shulepov, Y.V. Volatile probes for spectral research on silicate transformations. Theor Exp Chem 25, 219–222 (1989). https://doi.org/10.1007/BF01135016
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DOI: https://doi.org/10.1007/BF01135016