Skip to main content
SpringerLink
Log in

An increase in the number of ≡ Si-OH surface groups in layer silicates

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A significant amount (∼ 1.3%) of acid hydroxyl groups bonded to silicon atoms is present on the surface of chrysotile asbestos.

  2. 2.

    Disintegration of layer silicates by ultrasonics in an aqueous medium increases the number of acid hydroxyl groups on the surface.

  3. 3.

    The Tserevitinov-Terent'ev method for the determination of labile hydrogen is applicable to the quantitative determination of ≡ Si-OH groups on the surface of layer silicates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. H. Deuel, Ber. Deutsch. keram. Ges.31, 1 (1954).

    Google Scholar 

  2. J. Uytterhoeven, Silicates Industr.25, 403 (1960).

    Google Scholar 

  3. H. Deuel, G. Huber, and H. H. Günthard, Helv. chim. acta35, 1799 (1952).

    Google Scholar 

  4. D. J. Greenland and E. W. Russel, Trans. Faraday Soc.51, 1300 (1955).

    Google Scholar 

  5. V. P. Petrov and Yu. K. Andreev, Tr. Inst. geol. rudn. mestorozhd., petrogr., mineralogii i geokhimii, AN SSSR31, p. 5 (1959).

    Google Scholar 

  6. H. Deuel and G. Huber, Helv. chim. acta34, 1697 (1951).

    Google Scholar 

  7. A. P. Terent'ev and A. I. Kireeva, Izv. AN SSSR, Otd. khim. n. 172 (1951).

  8. W. A. Weyl, Research3, 230 (1950).

    PubMed  Google Scholar 

  9. R. E. Benson and J. E. Castle, J. Phys. Chem.62, 840 (1958).

    Google Scholar 

  10. H. Meyer, Analysis and Structural Determination of Organic Compounds [Russian translation], Kharkov-Kiev, p. 53 (1935).

  11. W. Biltz, Ber.40, 2182 (1907).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, USSR

    Yu. I. Skorik, K. G. Gileva, É. V. Kukharskaya & A. D. Fedoseev

Authors
  1. Yu. I. Skorik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. G. Gileva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. É. V. Kukharskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. D. Fedoseev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Skorik, Y.I., Gileva, K.G., Kukharskaya, É.V. et al. An increase in the number of ≡ Si-OH surface groups in layer silicates. Russ Chem Bull 12, 841–843 (1963). https://doi.org/10.1007/BF01134738

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01134738

Keywords

Search

Navigation