Summary
-
1.
The frequencies of the IR bands of the valence vibrations of electron-acceptor functional groups in mono -substituted derivatives of ferrocene are lowered and the integral intensities are noticeably increased in comparison with the corresponding derivatives of benzene.
-
2.
The integral intensities of the carbonyl bands in the derivatives of ferrocene that are disubstituted in different rings are lowered as a result of transmittal of the mutual influence of the substituents through the ferrocene nucleus.
This is a preview of subscription content, log in via an institution to check access.
Literature cited
A. V. Iogansen and É. V. Broun, Materials of the XIV Conference in Spectroscopy [in Russian] (in press, Gorkii).
E. B. Wilson and A. I. Wells, J. Chem. Phys.14, 578 (1946).
D. A. Ramsay, J. Amer. Chem. Soc.74, 72 (1952).
G. M. Barrow, J. Chem. Phys.21, 2008 (1953).
S. A. Francis, J. Chem. Phys.19, 942 (1951).
I. H. Mateos, R. Cetina, E. Olivera, and S. Meza, J. Organ. Chem.26, 7 (1961).
T. L. Brown, I. Regan, R. D. Schuetz, and I. S. Sternberg, J. Phys. Chem.63, 1324 (1959).
C. D. Schmulbach and R. S. Drago, J. Phys. Chem.64, 1956 (1960).
T. L. Brown, J. Amer. Chem. Soc.80, 794 (1958).
I. P. Iesson and H. W. Thompson, Spectrochim. acta13, 217 (1958).
A. N. Nesmeyanov, É. G. Perevalova, and R. V. Golovnya, Dokl. AN SSSR,103, 81 (1955).
M. R. Yagudaev and Yu. N. Sheinker, Dokl. AN SSSR144, 1, 173 (1962).
A. N. Nesmeyanov, É. G. Perevalova, R. V. Golovnya, and O. A. Nesmeyanova, Dokl. AN SSSR97, 459 (1954).
N. A. Nesmeyanov and O. A. Reutov, Dokl. AN SSSR115, 518 (1957).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dvoryantseva, G.G., Sheinker, Y.N. Integral intensities of IR bands characteristic of the vibrations of the functional groups in derivatives of ferrocene. Russ Chem Bull 12, 832–835 (1963). https://doi.org/10.1007/BF01134735
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01134735