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Preparation of aldehydes and ketones of the cyclopropylfuran series

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    2-(2-Methylcyclopropyl)furan and 2-(2-cyclopropylcyclopropyl)furan add to acrolein, crotonaldehyde, and mosityl oxide in an acid medium without cleavage of the cyclopropane ring with formation of the corresponding cyclopropylfuran aldehydes and ketones.

  2. 2.

    Aldehydes and ketones obtained in this way were subjected to Kizhner reduction with formation of 2-alkyl-5-(2-methylcyclopropyl)furans and 2-alkyl-5-(2-cyclopropylcyclopropyl)furans.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    V. G. Glukhovtsev, S. V. Zakharova & A. D. Petrov

Authors
  1. V. G. Glukhovtsev
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  2. S. V. Zakharova
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  3. A. D. Petrov
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Additional information

Raman spectra were determined by G. K. Gaivoronskaya, whom the authors thank.

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Glukhovtsev, V.G., Zakharova, S.V. & Petrov, A.D. Preparation of aldehydes and ketones of the cyclopropylfuran series. Russ Chem Bull 12, 816–821 (1963). https://doi.org/10.1007/BF01134732

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  • DOI: https://doi.org/10.1007/BF01134732

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