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Synthesis of aryl 2-nitrovinyl ketones [3-nitroacrylophenones], and the reactions of these compounds with nucleophilic reagents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A method was developed for the synthesis of aryl 2-nitrovinyl ketones (3-nitroacrylophenones) (Ar=C6H5, p-CH3C6H4, and p-BrC6H4.

  2. 2.

    A study was made of the reactions of these compounds with nucleophilic reagents (OCH −3 , CH3OH, OH−).

  3. 3.

    The possible mechanism of these reactions is discussed.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    M. I. Rybinskaya, L. V. Rybin & A. N. Nesmeyanov

Authors
  1. M. I. Rybinskaya
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  2. L. V. Rybin
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  3. A. N. Nesmeyanov
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Rybinskaya, M.I., Rybin, L.V. & Nesmeyanov, A.N. Synthesis of aryl 2-nitrovinyl ketones [3-nitroacrylophenones], and the reactions of these compounds with nucleophilic reagents. Russ Chem Bull 12, 810–815 (1963). https://doi.org/10.1007/BF01134731

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  • DOI: https://doi.org/10.1007/BF01134731

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