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Organoboron compounds

Communication 117. Reaction of amine complexes of (alkylthio)boranes with halogen derivatives of hydrocarbons and hydrogen chloride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By the action of halogen derivatives of hydrocarbons and of hydrogen chloride on dimethylamine-(alkylthio) boranes bis(dimethylamine)boronium salts are formed.

  2. 2.

    When treated with alkyl halides, complexes formed by (alkylthio)boranes with tertiary amines exchange their alkylthio group for halogen with formation of haloborane complexes.

  3. 3.

    Hydrogen chloride splits trialkylamine complexes of (alkylthio)boranes, and (alkylthio)borane trimers and amine hydrochlorides are formed.

  4. 4.

    Dimethylamine-(methylthio)borane reacts with dimethylamine hydrochloride with formation of bis(dimethylamine) boronium chloride.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    B. M. Mikhailov, T. A. Shchegoleva & V. D. Sheludyakov

Authors
  1. B. M. Mikhailov
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  2. T. A. Shchegoleva
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  3. V. D. Sheludyakov
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Mikhailov, B.M., Shchegoleva, T.A. & Sheludyakov, V.D. Organoboron compounds. Russ Chem Bull 12, 738–742 (1963). https://doi.org/10.1007/BF01134716

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  • DOI: https://doi.org/10.1007/BF01134716

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