Skip to main content
SpringerLink
Log in

The role of water in the formation of highly condensed silicates and germanates

Communication 3. Infrared absorption spectrum of synthetic afwillite

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The infrared absorption spectrum of synthetic afwillite was investigated in the region of 420–3500 cm−1.

  2. 2.

    Bands of the main valence vibrations of the complex anion [O3SiOH]3− and deformation vibrations of the hydroxyl were identified.

  3. 3.

    It was observed that the experimental data agree with the concept of the dual character of the Si-OH and particularly Si-O− bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. G. P. Stavitskaya and Ya. I. Ryskin, Optika i spektroskopiya,10, 343 (1961).

    Google Scholar 

  2. G. P. Stavitskaya and Ya. I. Ryskin, Izv. AN SSSR. Otd. khim. n., 1708 (1962).

  3. H. D. Megaw, Acta crystallogr.5, 477 (1952).

    Google Scholar 

  4. L. Heller, Acta crystallogr.5, 724 (1952).

    Google Scholar 

  5. N. V. Belov, Zh. strukt. khimii,1, 39 (1960).

    Google Scholar 

  6. Ya. I. Ryskin, Optika i spektroskopiya,7, 278 (1959).

    Google Scholar 

  7. Ya. I. Ryskin and G. P. Stavitskaya, Optika i spektroskopiya,7, 834 (1959).

    Google Scholar 

  8. Ya. I. Ryskin and G. P. Stavitskaya, Optika i spektroskopiya,8, 606 (1960).

    Google Scholar 

  9. Ya. I. Ryskin, G. P. Stavitskaya, and N. A. Toropov, Zh. neorgan. khimii,5, 2727 (1960).

    Google Scholar 

  10. H. E. Petch, N. Sheppard, and H. D. Megaw, Acta crystallogr.9, 29, (1956).

    Google Scholar 

  11. S. Brunauer, L. E. Copeland, and R. H. Bragg, J. Phys. Chem.60, 112 (1956).

    Google Scholar 

  12. G. Switzer, and E. H. Bailey, Amer. Mineralogist.38, 629 (1953).

    Google Scholar 

  13. H. W. F. Taylor and L. Heller, Cryst. data for the calc. silic., HMSO, London (1956).

    Google Scholar 

  14. Ya. I. Ryskin, Optika i spektroskopiya,12, 518 (1962).

    Google Scholar 

  15. E. Thilo, H. Funk, and M. Wichman, Abhandl. Dtsch. Akad. Wiss. Berl. Kl. Math. und allgem. Naturwiss., No. 4, 1 (1950); Coll. of articles “Physical chemistry of silicates,” [Russian translation], Izd. inostr. lit. p. 5 (1956).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, Academy of Sciences USSR, USSR

    Ya. I. Ryskin & G. P. Stavitskaya

Authors
  1. Ya. I. Ryskin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. P. Stavitskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

See [1] for communication 1 and [2] for communication 2.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ryskin, Y.I., Stavitskaya, G.P. The role of water in the formation of highly condensed silicates and germanates. Russ Chem Bull 12, 719–722 (1963). https://doi.org/10.1007/BF01134712

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01134712

Keywords

Search

Navigation