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Nitrogen impurity centers in synthetic diamond powder

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Abstract

The ESR spectrum is reported for the nitrogen donors in polycrystalline synthetic diamond at room temperature; g is 2.0025±0.005. The moments method is used to examine the unsymmetrical secondary peaks, which give the constants for the coupling between the electron and the nuclear magnetic moment; these agree satisfactorily with those for a single crystal of natural diamond. The nitrogen donor concentration is found to be 1018–1019 cm−3. The IR spectrum has a band at 9.1Μ, which is more prominent for the synthetic material; this appears to be due to multiple nitrogen centers.

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Authors and Affiliations

  1. Ukrainian Research Institute for Synthetic Superhard Materials, Kiev

    G. S. Danil'chuk, L. N. Ganyuk, A. E. Koval'skii, P. P. Pogoretskii, G. A. Podzyarei & L. A. Shul'man

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  1. G. S. Danil'chuk
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  2. L. N. Ganyuk
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  3. A. E. Koval'skii
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  4. P. P. Pogoretskii
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  5. G. A. Podzyarei
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  6. L. A. Shul'man
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Danil'chuk, G.S., Ganyuk, L.N., Koval'skii, A.E. et al. Nitrogen impurity centers in synthetic diamond powder. Theor Exp Chem 1, 237–240 (1965). https://doi.org/10.1007/BF01134327

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  • DOI: https://doi.org/10.1007/BF01134327

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