Abstract
Measurements have been made on the temperature coefficient of the equilibrium constant for the formation of diphenylsodium in tetrahydrofuran and in ethers of ethylene glycol; electrical conductivity measarements are reported for solutions of naphthylsodium. The thermodynamic and dissociation constants are discussed in relation to the solvation mechanisms of sodium ions in esters.
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Petrov, E.S., Shatenshtein, A.N. The solvation mechanism for sodium ions in some ethers in the formation of anion radicals. Theor Exp Chem 1, 223–225 (1965). https://doi.org/10.1007/BF01134324
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DOI: https://doi.org/10.1007/BF01134324