Abstract
The electrostatic interaction is calculated for the dipoles in 1,1-dichloroethylene, dichloroaryl compounds, and some alicyclic 1,2-dihalo compounds and α-haloketones. The induced dipoles, bond moments, and molecular dipole moments are calculated. Most of the results agree well with experiment. The induction is found to be dependent on the separation and mutual orientation of the dipoles rather than on the number of bonds between them. It is concluded that the field effect is decisive in induction and that transmission via chains of atoms is relatively unimportant.
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Vereshchagin, A.N., Vul'fson, S.G. Calculation of the inductive interaction of two dipoles. Theor Exp Chem 1, 195–198 (1965). https://doi.org/10.1007/BF01134320
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DOI: https://doi.org/10.1007/BF01134320