Skip to main content
Log in

Thermodynamic properties of aqueous solutions at high temperatures: Needs, methods, and challenges

  • Published:
International Journal of Thermophysics Aims and scope Submit manuscript

Abstract

Needs exist for thermophysical data on aqueous solutions at high temperatures and pressures in many different areas of science and engineering. These needs are reviewed and references are given to recent relevant conference proceedings, reviews, and papers. Aspects and drawbacks are discussed of current methods, which are most often extensions to high temperatures of methods developed for liquid water. The challenges posed by engineering needs and by new phenomena resulting from experimental breakthroughs are discussed. Some examples are given of alternative approaches more suitable for highly compressible media.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Papers by S. L. Phillips et al., J. A. Rard, S. J. Sanders, and M. Rafal, C. C. Chen et al., J. S. Dweck et al., A. L. Smith, J. R. Morrey et al., and T. J. Wolery, inProceedings of the International Conference on Thermodynamics of Aqueous Systems with Industrial Applications, Airlie House, VA, 1987. N. C. Scrivner, ed. (Hemisphere, Washington, D. C., 1990).

  2. R. C. Wilhoit, inThermodynamics of Aqueous Systems with Industrial Applications, ACS Symposium Series 133, S. A. Newman, ed. (ACS, Washington, D.C., 1980), p. 451.

    Google Scholar 

  3. S. Sourirajan and G. C. Kennedy,Am. J. Sci. 260:115 (1962).

    Google Scholar 

  4. R. W. Potter and M. A. Clynne,J. Soln. Chem. 7:837 (1978).

    Google Scholar 

  5. J. L. Bischoff, R. J. Rosenbauer, and K. S. Pitzer,Geochim. Cosmochim. Acta 50:1437 (1986).

    Google Scholar 

  6. J. C. Tanger, IV, and H. C. Helgeson,Am. J. Svi. 288:19 (1986).

    Google Scholar 

  7. H. Renon, ed.,Fluid Properties and Phase Equilibria for Process Design, Proc. 4th Int. Conf., Helsingor, Denmark, May 1986, Fluid Phase Equil. 29 and 30. (Elsevier, Amsterdam, 1986).

    Google Scholar 

  8. N. C. Scrivner, ed.,Proceedings of the International Conference on Thermodynamics of Aqueous Systems with Industrial Applications, Airlie House, VA, 1987. (Hemisphere, Washington, D.C., 1990).

    Google Scholar 

  9. Symposium an Chemistry in High Temperature Aqueous Solutions, Provo, Utah, Aug. 1987, R. Izatt, ed., (EPRI, 1990).

  10. G. Maurer, inFluid Properties and Phase Equilibria for Chemical Process Design, H. Renon, ed.,Fluid Phase Equil. 30:337 (1986).

  11. D. J. Turner, inThermodynamics of Aqueous Systems with Industrial Applications, ACS Symposium Series 133, S. A. Newman, ed. (ACS, Washington, D. C., 1980), p. 653.

    Google Scholar 

  12. H. C. Helgeson, D. H. Kirkham, and G. C. Flowers,Am. J. Sci. 281:1294 (1981).

    Google Scholar 

  13. R. H. Busey, H. F. Holmes, and R. E. Mesmer,J. Chem. Thermodyn. 19:343 (1984).

    Google Scholar 

  14. D. Smith-Magowan and R. H. Wood,J. Chem. Thermodyn. 13:1047 (1981).

    Google Scholar 

  15. D. E. White, R. H. Wood, and D. R. Biggerstaff,J. Chem. Thermodyn. 20:159 (1988).

    Google Scholar 

  16. D. R. Biggerstaff and R. H. Wood,J. Phys. Chem. 92:1994 (1988).

    Google Scholar 

  17. E. U. Franck, inPhase Equilibria and Fluid Properties in the Chemical Industry, ACS Symposium Series 60, T. S. Storvick and S. I. Sandler, eds. (ACS, Washington, D.C., 1977), p. 99.

    Google Scholar 

  18. E. U. Franck, J. E. Savoleian, and W. L. Marshall,Rev. Sci. Instr. 33:115 (1962); A. S. Quist and W. L. Marshall,J. Phys. Chem. 72:684 (1968).

    Google Scholar 

  19. K. Heger, Ph.D. thesis (Karlsruhe, 1969); M. Uematsu and E. U. Franck,J. Phys. Chem. Ref. Data 9:1291 (1980).

  20. W. M. Marshall and E. V. Jones,J. Inorg. Nucl. Chem. 36:2313 (1974).

    Google Scholar 

  21. I. Kh. Khaibullin and N. M. Borisov,Teplofiz. Vysok. Temp. 4:518 (1966).

    Google Scholar 

  22. M. Heilig and E. U. Franck,Ber. Bunsenges. Phys. Chem. 93:898 (1989).

    Google Scholar 

  23. K. S. Pitzer,J. Phys. Chem. 88:2689 (1984);Rev. Mineral. 17:97 (1987).

    Google Scholar 

  24. H. L. Friedman, inWater and Aqueous Solutions, G. W. Neilson and J. E. Enderby, eds. (Hilger, Boston, 1986), p. 117.

    Google Scholar 

  25. K. S. Pitzer, J. C. Peiper, and R. H. Busey,J. Phys. Chem. Ref. Data 13:1 (1984).

    Google Scholar 

  26. G. Morrison, J. M. H. Levelt Sengers, R. F. Chang, and J. J. Christensen, inSupercritical Fluid Technology, J. M. L. Penninger et al., eds. (Elsevier, Amsterdam, 1985), p. 25.

    Google Scholar 

  27. R. F. Chang, G. Morrison, and J. M. H. Levelt Sengers,J. Phys. Chem. 88:3389 (1984).

    Google Scholar 

  28. J. M. H. Levelt Sengers, C. M. Everhart, G. Morrison, and K. S. Pitzer,Chem. Eng. Comm. 47:315 (1986).

    Google Scholar 

  29. P. Debye and E. Hückel,Phys. Z. 24:1426 (1923).

    Google Scholar 

  30. R. Crovetto and R. Fernandez-Prini,J. Phys. Chem. Ref. Data (in press).

  31. M. L. Japas and J. M. H. Levelt Sengers,AIChE J. March (1989).

  32. M. L. Japas and E. U. Franck,Ber. Bunsenges. Phys. Chem. 89:793 (1985).

    Google Scholar 

  33. L. Haar, J. S. Gallagher, and G. S. Kell,NBS-NRC Steam Tables (Hemisphere, Washington, D.C., 1984).

    Google Scholar 

  34. K. S. Pitzer and J. C. Tanger, IV,Proc. 10th Symp. Thermophys. Prop., A. Cezairliyan and J. V. Sengers, eds.,Int. J. Thermophys. 9: 635 (1988).

  35. J. S. Gallagher and J. M. H. Levelt Sengers,Proc. 10th Symp. Thermophys. Prop., A. Cezairliyan and J. V. Sengers, eds.,Int. J. Thermophys. 9:649 (1988).

  36. J. C. Tanger, IV, and K. S. Pitzer,Geochim. Cosmochim. Acta 53:973 (1989).

    Google Scholar 

  37. Z. Y. Chen, A. Abbaci, and J. V. Sengers,Proc. 11th Int. Conf. Prop. Steam, Prague 1989, O. Sifner, ed., (Hemisphere, Washington, D.C., 1990).

    Google Scholar 

  38. K. S. Pitzer,J. Phys. Chem. 90:1502 (1986).

    Google Scholar 

  39. M. L. Japas and J. M. H. Levelt Sengers,J. Phys. Chem. (submitted).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Levelt Sengers, J.M.H. Thermodynamic properties of aqueous solutions at high temperatures: Needs, methods, and challenges. Int J Thermophys 11, 399–415 (1990). https://doi.org/10.1007/BF01133570

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01133570

Key words

Navigation