Skip to main content
Log in

Study of H and BF2 chelates of a number OF α- AND β-substituted acyclic β-dicarbonyl compounds by the1H and13C NMR method

  • Brief Communications
  • Published:
Theoretical and Experimental Chemistry Aims and scope

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literature cited

  1. N. N. Shapet'ko, S. S. Berestova, V. G., Medvedeva, A. P. Skoldinov, and Yu. S. Andreichikov, “Method of determining the position of the proton in the intramolecular hydrogen bond according to the13C NMR spectra of chelate compounds,” Dokl. Akad. Nauk SSSR,234, No. 4, 876–879 (1977).

    Google Scholar 

  2. G. C. Levy and G. L. Nelson, Carbon-Thirteen Nuclear Magnetic Resonance for Organic Chemists, Wiley (1972).

  3. N. N. Shapet'ko, S. S. Berestova, G. M. Lukovkin, and Yu. S. Bagachev, “13C NMR study of the enol forms of β-diketones,” Org. Magn. Resonance,7, No. 5, 237–239 (1975).

    Google Scholar 

  4. N. N. Shapet'ko, L. N. Kurkovskaya, V. G. Medvedeva, A. P. Skoldinov, and L. K. Vasyanina, “NMR of BF2 chelates of β-di- and β,β'-tricarbonyl compounds,” Zh. Strukt. Khim.,10, No. 5, 936–938 (1969).

    Google Scholar 

  5. J. C. Hammal and J. A. S. Smith, “Electric field effects in magnetic resonance. I.13C chemical shifts,” J. Chem. Soc., A, No. 19, 2883–2887 (1969).

    Google Scholar 

  6. Tables of Interatomic Distances and Configurations in Molecules and Ions, Burlington House, London, Vol. 1, No. 11 (1958), p. 387.

  7. A. E. Shugam and L. M. Shkol'nikova, “New data on the stereochemistry of internal complex compounds,” in: Crystal Chemistry, 1965, Results of Science [in Russian], Moscow (1967), pp. 5–103.

  8. A. H. Lowrey, C. George, P. D'Antonio, and J. Karle, “Structure of acetylacetone by electron diffraction,” J. Am. Chem. Soc.,93, No. 23, 6399–6403 (1971).

    Google Scholar 

  9. A. L. Andreassen and S. H. Bauer, “The structures of acetylacetone, trifluoroacetylacetone, and trifluoroacetone,” J. Molec. Struct.,12, No. 3, 381–393 (1972).

    Google Scholar 

  10. D. N. Shigorin, E. A. Gastilovich, T. S. Kopteva, and N. M. Viktorova, “Study of nonplanar vibrations of the enol form of acetylacetone,” Opt. Spektrosk.,28, No. 2, 241–247 (1970).

    Google Scholar 

  11. N. N. Shapet'ko,“NMR study of the influence of β substituents on the intramolecular hydrogen bond in β-dicarbonyl compounds,” Org. Magn. Resonance,5, No. 5, 215–216 (1973).

    Google Scholar 

  12. W. F. Rowe, R. W. Duerst, and E. B. Wilson, “The intramolecular hydrogen bond in malonaldehyde,” J. Am. Chem. Soc.,98, No. 13, 4021–4023 (1976).

    Google Scholar 

  13. Sh. Kato, H. Kato, and K. Fukui, “Theoretical treatment on the behavior of the hydrogenbonded proton in malonaldehyde,” J. Am. Chem. Soc.,99, No. 3, 684–691 (1977).

    Google Scholar 

  14. M. J. T. Robinson, K. M. Rosen, and J. D. B. Workman, “Isotope effects. I. Hydrogen isotope effects in acetylacetone and its enol,” Tetrahedron,33, No. 13, 1655–1661 (1977).

    Google Scholar 

  15. N. N. Shapet'ko, Yu. S. Bogachev, I. L. Radushnova, and D. N. Shigorin, “Investigation of the type of potential-energy function of the proton in strong intramolecular hydrogen bonds by the1H,2D, and13C NMR and MO LCAO methods in the CNDO/2 approximation,” Dokl. Akad. Nauk SSSR,231, No. 2, 409–412 (1976).

    Google Scholar 

  16. A. I. Kol'tsov and G. M. Kheifets, “Study of tautomerism with the aid of nuclear magnetic resonance spectra,” Usp. Khim.,41, No. 5, 877–908 (1972).

    Google Scholar 

  17. S. I. Chan, L. Lin, D. Clutter, and P. Dea, “The anomalous deuterium isotope effect on the chemical shift of the bridge hydrogen in the enol tautomer of 2, 4-pentanedione,” Proc. Nat. Acad. Sci.,65, No. 4, 816–822 (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 15, No. 5, pp. 575–580, September–October, 1979.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Berestova, S.S., Shapet'ko, N.N., Shigorin, D.N. et al. Study of H and BF2 chelates of a number OF α- AND β-substituted acyclic β-dicarbonyl compounds by the1H and13C NMR method. Theor Exp Chem 15, 449–454 (1979). https://doi.org/10.1007/BF01128425

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01128425

Navigation