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Ligating properties oftert-phosphine/arsine sulphides or selenides, Part IX. Preparation and spectroscopic studies of copper(I)/copper(II) complexes with bis(—phosphine chalcogenides)

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Summary

The analytical, molar conductance and spectroscopic studies of new complexes of copper(I) and copper(II) with bis(—phosphine chalcogenides), Ph2P(E)(CH2)n-P(E)Ph2(L-L) are reported. The complexes are of the types: (a) [CuX(L-L)](X, n, E: Cl, 2–4, Br, 2, S; Cl, Br, 1, Se); (b) [Cu2X2(L-L)] (X, n, E: Cl, Br, 2, 3, Se) and (c) [CuCl2(L-L)] (n, E: 2, 3, S). Possible structures have been derived.

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  1. Department of Chemistry, Guru Nanak Dev University, 143005, Amritsar, India

    Tarlok S. Lobana

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Lobana, T.S. Ligating properties oftert-phosphine/arsine sulphides or selenides, Part IX. Preparation and spectroscopic studies of copper(I)/copper(II) complexes with bis(—phosphine chalcogenides). Transition Met Chem 16, 57–59 (1991). https://doi.org/10.1007/BF01127872

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  • DOI: https://doi.org/10.1007/BF01127872

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